Alternative Coinitiators Applicable to Photocurable Resin Composites
The composite resins available on the market
today are mostly light-cured resins. So, photoinitiator molecules are included
in these materials which have the ability to absorb light, and as result,
generate free radicals which initiate the polymerization of these resin
materials.
The light curing systems most commonly employed in the composites
are the camphorquinone/amine system. The photoinitiator is camphorquinone,
which requires a coinitiator to perform the polymerization process. Tertiary
amines (aliphatic or aromatic) do not absorb light, but interact with the
activated camphorquinone to produce reactive species. However, this
photoinitiator system has some disadvantages, such as the tendency to promote
yellowing to resin materials low compatibility with oral tissues and even mutagenic characteristics.
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